Studies on the mechanism of the reaction between 5�-deoxyadenosylcobinamide and cyanide.
Date
2002
Authors
Brasch, Nicola E
Cregan, Andrew
Vanselow, Mary
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
The reaction between 5′-deoxyadenosylcobinamide (AdoCbi+OH-) and cyanide (NaCN or tetrabutylammonium cyanide) to form dicyanocobinamide, adenine and 1-cyano-D-erythro-2,3-dihydroxy-4-pentenol has been studied by 1H NMR and UV-visible spectroscopies in a
Description
Keywords
Keywords: Chemical bonds; Cyanides; Negative ions; Nuclear magnetic resonance spectroscopy; Organic solvents; pH effects; Rate constants; Ultraviolet spectroscopy; X ray crystallography; Chemical shifts; Organic compounds
Citation
Collections
Source
Dalton Transactions
Type
Journal article