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A zinc(II) tetraphenylporphyrin peripherally functionalized with redox-active " trans -[(η 5 -C 5 H 5 )Fe(η 5 -C 5 H 4 )C≡C](κ 2 -dppe) 2 Ru(C≡C)-" substituents: linear electrochromism and third-order nonlinear optics

Merhi, Areej; Grelaud, Guillaume; Ripoche, Nicholas; Barlow, Adam; Cifuentes, Marie; Humphrey, Mark; Paul, Frederic; Paul-Roth, Christine


A nonametallic organometallic-coordination complex (4), assembled from redox-active ferrocenyl (Fc) and Ru(κ2-dppe)2 fragments (dppe = 1,2-bis(diphenylphosphino)ethane) as peripheral donor groups and a central Zn(II) tetraphenylporphyrin (ZnTPP) core, ha

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Polyhedron
DOI: 10.1016/j.poly.2014.05.013


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