Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants
Equilibrium constants in Cu-based atom transfer radical polymerization (ATRP) were determined for a wide range of ligands and initiators in acetonitrile at 22°C. The ATRP equilibrium constants obtained vary over 7 orders of magnitude and strongly depend
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|Source:||Journal of the American Chemical Society|
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