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Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants

Tang, Wei; Kwak, Yungwan; Braunecker, Wade; Tsarevsky, Nicolay V.; Coote, Michelle; Matyjaszewski, Krzysztof


Equilibrium constants in Cu-based atom transfer radical polymerization (ATRP) were determined for a wide range of ligands and initiators in acetonitrile at 22°C. The ATRP equilibrium constants obtained vary over 7 orders of magnitude and strongly depend

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja802290a


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