Thiocarbonylphosphorane and arsorane ligands
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Burt, Liam
Hill, Anthony
Jones, Stephanie
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Royal Society of Chemistry
Abstract
Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR3 (A = P, As) are observed in the salts [W(η2-C,S-SCAR3)(CO)2(Tp*)]PF6 [AR3 = PCy3, PMenPh3-n: n = 0, 1, 2, AsMePh2; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR3)(CO)2(Tp*)]+ with sulfur.
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Chemical communications
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Open Access
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Restricted until
2023-10-04
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