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Thiocarbonylphosphorane and arsorane ligands

Burt, Liam; Hill, Anthony; Jones, Stephanie


Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR3 (A = P, As) are observed in the salts [W(η2-C,S-SCAR3)(CO)2(Tp*)]PF6 [AR3 = PCy3, PMenPh3-n: n = 0, 1, 2, AsMePh2; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR3)(CO)2(Tp*)]+ with sulfur.

CollectionsANU Research Publications
Date published: 2022-10-04
Type: Journal article
Source: Chemical communications
DOI: 10.1039/d2cc03747e
Access Rights: Open Access


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