Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Thiocarbonylphosphorane and arsorane ligands

Thumbnail Image

Date

2022-10-04

Authors

Burt, Liam
Hill, Anthony
Jones, Stephanie

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR3 (A = P, As) are observed in the salts [W(η2-C,S-SCAR3)(CO)2(Tp*)]PF6 [AR3 = PCy3, PMenPh3-n: n = 0, 1, 2, AsMePh2; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR3)(CO)2(Tp*)]+ with sulfur.

Description

Keywords

crystallography, x-ray, ligands, models, molecular, sulfur, borates, salts

Citation

URI

http://hdl.handle.net/1885/282555

Collections

ANU Research Publications

Source

Chemical communications

Type

Journal article

Book Title

Entity type

Access Statement

Open Access

License Rights

DOI

10.1039/d2cc03747e

Restricted until

2023-10-04

Downloads

File
Description
10.1039_D2CC03747E Thiocarbonylphosphoranes.pdf (2.3 MB)

DSpace software copyright © 2002-2026 LYRASIS