Optical spectroscopy of Er doped Si-nanocrystals on sapphire substrates fabricated by ion-implantation into SiO2

Date

2010

Authors

Hylton, N. P.
Crowe, I. F.
Knights, Andrew P.
Halsall, M. P.
Ruffell, Simon
Gwilliam, R.

Journal Title

Journal ISSN

Volume Title

Publisher

Society of Photo-Optical Instrumentation Engineers

Abstract

We present the results of an optical investigation of a series of Er doped silicon nanocrystal (Si-NC) samples which were fabricated via ion implantation into SiO2 on sapphire substrates, followed by a range of rapid thermal processing. The photoluminescence spectra of the Si-NC emission revealed an increase in luminescence intensity and a red-shift of the peak wavelength as a function of annealing conditions. We attribute the former effect to the reduction of implantation induced defects with increasing annealing temperature/duration. Measurements of the rate of decay of photoluminescence intensity at room temperature show a corresponding increase in the carrier lifetimes which is also an indication of a reduced contribution from non-radiative centers. The red-shift of the peak Si-NC intensity is ascribed to an increasing mean Si-NC size as a function of the annealing conditions. Also presented is an estimation of the relative Er sensitization which reveals that the smallest Si-NC size distribution leads to the greatest sensitization ratio. Further investigation in the form of excitation spectroscopy was used to show that Er ions are sensitized not only by energy transfer from the Si-NCs, but also, crucially, from defect states in the SiO2.

Description

Keywords

Annealing condition, Er sensitization, Er-doped, Erbium ion, Defect state, Excitation spectroscopy, Implantation-induced defects, Luminescence intensity, Nonradiative centers, Optical investigation, Optical spectroscopy, Peak wavelength, Photoluminescence Erbium, Ion implantation, Photoluminescence, Rapid thermal annealing, Silicon nanocrystals

Citation

Source

Silicon Photonics V: Proceedings of the Society of Photo-optical Instrumentation Engineers

Type

Conference paper

Book Title

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