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A Cyclodextrin-Based Photoresponsive Molecular Gate that Functions Independently of Either Solvent or Potentially Competitive Guests

Loh, Ka-Heng; Smith, Nicole; Onagi, Hideki; Lincoln, Stephen F; Easton, Christopher

Description

The photoinduced interconversion between cinnamido-substituted cyclodextrins constitutes a gating switch through which the substituent moves to open or block access to the cyclodextrin cavity. Most unusually for a cyclodextrin-based device, the operation of this gate is solvent-independent and unaffected by potentially competitive guests. It occurs in MeOH and DMSO, as well as in water. This contrasts with other cyclodextrin inclusion phenomena that are usually driven by hydrophobic effects and...[Show more]

dc.contributor.authorLoh, Ka-Heng
dc.contributor.authorSmith, Nicole
dc.contributor.authorOnagi, Hideki
dc.contributor.authorLincoln, Stephen F
dc.contributor.authorEaston, Christopher
dc.date.accessioned2016-06-14T23:20:09Z
dc.identifier.issn1861-4728
dc.identifier.urihttp://hdl.handle.net/1885/103235
dc.description.abstractThe photoinduced interconversion between cinnamido-substituted cyclodextrins constitutes a gating switch through which the substituent moves to open or block access to the cyclodextrin cavity. Most unusually for a cyclodextrin-based device, the operation of this gate is solvent-independent and unaffected by potentially competitive guests. It occurs in MeOH and DMSO, as well as in water. This contrasts with other cyclodextrin inclusion phenomena that are usually driven by hydrophobic effects and limited to aqueous media.
dc.publisherWiley-VCH Verlag GMBH
dc.sourceChemistry - An Asian Journal
dc.titleA Cyclodextrin-Based Photoresponsive Molecular Gate that Functions Independently of Either Solvent or Potentially Competitive Guests
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume10
dc.date.issued2015
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationU3488905xPUB5747
local.type.statusPublished Version
local.contributor.affiliationLoh, Ka-Heng, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSmith, Nicole, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationOnagi, Hideki, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLincoln, Stephen F, University of Adelaide
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue11
local.bibliographicCitation.startpage2328
local.bibliographicCitation.lastpage2332
local.identifier.doi10.1002/asia.201500696
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-06-14T08:46:17Z
local.identifier.scopusID2-s2.0-84945457757
CollectionsANU Research Publications

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