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A Cyclodextrin-Based Photoresponsive Molecular Gate that Functions Independently of Either Solvent or Potentially Competitive Guests

dc.contributor.authorLoh, Ka-Heng
dc.contributor.authorSmith, Nicole
dc.contributor.authorOnagi, Hideki
dc.contributor.authorLincoln, Stephen F
dc.contributor.authorEaston, Christopher
dc.date.accessioned2016-06-14T23:20:09Z
dc.date.issued2015
dc.date.updated2021-08-01T08:29:52Z
dc.description.abstractThe photoinduced interconversion between cinnamido-substituted cyclodextrins constitutes a gating switch through which the substituent moves to open or block access to the cyclodextrin cavity. Most unusually for a cyclodextrin-based device, the operation of this gate is solvent-independent and unaffected by potentially competitive guests. It occurs in MeOH and DMSO, as well as in water. This contrasts with other cyclodextrin inclusion phenomena that are usually driven by hydrophobic effects and limited to aqueous media.
dc.identifier.issn1861-4728
dc.identifier.urihttp://hdl.handle.net/1885/103235
dc.publisherWiley-VCH Verlag GMBH
dc.sourceChemistry - An Asian Journal
dc.titleA Cyclodextrin-Based Photoresponsive Molecular Gate that Functions Independently of Either Solvent or Potentially Competitive Guests
dc.typeJournal article
local.bibliographicCitation.issue11
local.bibliographicCitation.lastpage2332
local.bibliographicCitation.startpage2328
local.contributor.affiliationLoh, Ka-Heng, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSmith, Nicole, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationOnagi, Hideki, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLincoln, Stephen F, University of Adelaide
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidLoh, Ka-Heng, u4806220
local.contributor.authoruidSmith, Nicole, u5105705
local.contributor.authoruidOnagi, Hideki, u9718356
local.contributor.authoruidEaston, Christopher, u9500570
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationU3488905xPUB5747
local.identifier.citationvolume10
local.identifier.doi10.1002/asia.201500696
local.identifier.scopusID2-s2.0-84945457757
local.identifier.thomsonID000363472800002
local.type.statusPublished Version

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