Asymmetric aldol reactions using boron enolates: Applications to polyketide synthesis
| dc.contributor.author | Paterson, Ian | en |
| dc.contributor.author | Doughty, Victoria A. | en |
| dc.contributor.author | Florence, Gordon | en |
| dc.contributor.author | Gerlach, Kai | en |
| dc.contributor.author | McLeod, Malcolm D. | en |
| dc.contributor.author | Scott, Jeremy P. | en |
| dc.contributor.author | Trieselmann, Thomas | en |
| dc.date.accessioned | 2026-01-01T09:40:59Z | |
| dc.date.available | 2026-01-01T09:40:59Z | |
| dc.date.issued | 2001 | en |
| dc.description.abstract | The chiral boron enolates 7-14 add to aldehydes with high levels of stereocontrol in a predictable sense. These enolates are designed specifically for the aldol-based construction of the highly oxygenated and stereochemically challenging structures found in polyketide natural products, as illustrated here by their application to the total synthesis of concanamycin F and discodermolide. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 12 | en |
| dc.identifier.issn | 0097-6156 | en |
| dc.identifier.scopus | 0042850737 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733799426 | |
| dc.language.iso | en | en |
| dc.source | ACS Symposium Series | en |
| dc.title | Asymmetric aldol reactions using boron enolates: Applications to polyketide synthesis | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 206 | en |
| local.bibliographicCitation.startpage | 195 | en |
| local.contributor.affiliation | Paterson, Ian; University of Cambridge | en |
| local.contributor.affiliation | Doughty, Victoria A.; University of Cambridge | en |
| local.contributor.affiliation | Florence, Gordon; University of Cambridge | en |
| local.contributor.affiliation | Gerlach, Kai; University of Cambridge | en |
| local.contributor.affiliation | McLeod, Malcolm D.; University of Cambridge | en |
| local.contributor.affiliation | Scott, Jeremy P.; University of Cambridge | en |
| local.contributor.affiliation | Trieselmann, Thomas; University of Cambridge | en |
| local.identifier.ariespublication | u4005981xPUB278 | en |
| local.identifier.citationvolume | 783 | en |
| local.identifier.doi | 10.1021/bk-2001-0783.ch014 | en |
| local.identifier.pure | 16fd37e6-2ee2-4f02-ab8a-3e749237de4b | en |
| local.identifier.url | https://www.scopus.com/pages/publications/0042850737 | en |
| local.type.status | Published | en |