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Insights into D<sub>4h</sub>@metal-symmetry single-molecule magnetism: the case of a dysprosium-bis(boryloxide) complex

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dc.contributor.authorThomas-Hargreaves, Lewis R.en
dc.contributor.authorHunger, Daviden
dc.contributor.authorKern, Michalen
dc.contributor.authorWooles, Ashley J.en
dc.contributor.authorVan Slageren, Jorisen
dc.contributor.authorChilton, Nicholas F.en
dc.contributor.authorLiddle, Stephen T.en
dc.date.accessioned2025-05-30T05:31:05Z
dc.date.available2025-05-30T05:31:05Z
dc.date.issued2020-11-12en
dc.description.abstractWe report the synthesis of the lanthanide-(bis)boryloxide complex [Dy{OB(NArCH)2}2(THF)4][BPh4] (2Dy, Ar = 2,6-Pri2C6H3), with idealised D4h@Dy(III) point-group symmetry. Complex 2Dy exhibits single-molecule magnetism (SMM), with one of the highest energy barriers (Ueff = 1565(298) K) of any six-coordinate lanthanide-SMM. Complex 2Dy validates electrostatic model predictions, informing the future design of lanthanide-SMMs.en
dc.description.statusPeer-revieweden
dc.format.extent4en
dc.identifier.issn1359-7345en
dc.identifier.otherBibtex:thomas-hargreaves_insights_2021en
dc.identifier.scopus85100233960en
dc.identifier.urihttps://hdl.handle.net/1885/733754685
dc.language.isoenen
dc.sourceChemical Communicationsen
dc.titleInsights into D<sub>4h</sub>@metal-symmetry single-molecule magnetism: the case of a dysprosium-bis(boryloxide) complexen
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.lastpage736en
local.bibliographicCitation.startpage733en
local.contributor.affiliationThomas-Hargreaves, Lewis R.; University of Manchesteren
local.contributor.affiliationHunger, David; University of Stuttgarten
local.contributor.affiliationKern, Michal; University of Stuttgarten
local.contributor.affiliationWooles, Ashley J.; University of Manchesteren
local.contributor.affiliationVan Slageren, Joris; University of Stuttgarten
local.contributor.affiliationChilton, Nicholas F.; University of Manchesteren
local.contributor.affiliationLiddle, Stephen T.; University of Manchesteren
local.identifier.citationvolume57en
local.identifier.doi10.1039/D0CC07446Ben
local.identifier.pure06dd6297-0d5b-4666-9337-a6addfede2b6en
local.type.statusPublisheden

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