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Insights into D<sub>4h</sub>@metal-symmetry single-molecule magnetism: the case of a dysprosium-bis(boryloxide) complex

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2020-11-12

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Thomas-Hargreaves, Lewis R.
Hunger, David
Kern, Michal
Wooles, Ashley J.
Van Slageren, Joris
Chilton, Nicholas F.
Liddle, Stephen T.

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We report the synthesis of the lanthanide-(bis)boryloxide complex [Dy{OB(NArCH)2}2(THF)4][BPh4] (2Dy, Ar = 2,6-Pri2C6H3), with idealised D4h@Dy(III) point-group symmetry. Complex 2Dy exhibits single-molecule magnetism (SMM), with one of the highest energy barriers (Ueff = 1565(298) K) of any six-coordinate lanthanide-SMM. Complex 2Dy validates electrostatic model predictions, informing the future design of lanthanide-SMMs.

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https://hdl.handle.net/1885/733754685

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ANU Research Publications

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Chemical Communications

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10.1039/D0CC07446B

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