Phospha-alkyne hydro-osmiation:: synthesis of [Os{κ<SUP>1</SUP><i>P</i>,κ<SUP>1</SUP><i>P</i>′-P=CRP(=CHR)}Cl(CO)(PPh<sub>3</sub>)<sub>2</sub>](R = CMe<sub>3</sub>)
| dc.contributor.author | Hill, AF | en |
| dc.contributor.author | Jones, C | en |
| dc.contributor.author | Wilton-Ely, JDET | en |
| dc.date.accessioned | 2026-06-02T12:53:27Z | |
| dc.date.available | 2026-06-02T12:53:27Z | |
| dc.date.issued | 1999-03-07 | en |
| dc.description.abstract | The reaction of [OsHCl(CO)(PPh3)(2)(BTD)] (BTD = 2,1,3-benzothiadiazole) with P=CCMe3 provides the novel complex [Os{kappa(1)P,kappa(1)P'-P=CRP(=CHR)Cl(CO)(PPh3)(2)] (R = CMe3) which features both phospha-alkenyl and phosphaalkene donors within the same metallacycle. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 2 | en |
| dc.identifier.issn | 1359-7345 | en |
| dc.identifier.other | WOS:000079097200026 | en |
| dc.identifier.other | ORCID:/0000-0003-2167-0604/work/181882264 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733809897 | |
| dc.language.iso | en | en |
| dc.source | Chemical Communications | en |
| dc.subject | X-ray structure | en |
| dc.subject | Crystal-structure | en |
| dc.subject | Complexes | en |
| dc.subject | Ruthenium(ii) | en |
| dc.title | Phospha-alkyne hydro-osmiation:: synthesis of [Os{κ<SUP>1</SUP><i>P</i>,κ<SUP>1</SUP><i>P</i>′-P=CRP(=CHR)}Cl(CO)(PPh<sub>3</sub>)<sub>2</sub>](R = CMe<sub>3</sub>) | en |
| dc.type | Commentary | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 452 | en |
| local.bibliographicCitation.startpage | 451 | en |
| local.contributor.affiliation | Hill, AF; Chemistry Research, Research School of Chemistry, ANU College of Science and Medicine, The Australian National University | en |
| local.contributor.affiliation | Jones, C; Mathematics Programs, Mathematical Sciences Institute, ANU College of Systems and Society, The Australian National University | en |
| local.contributor.affiliation | Wilton-Ely, JDET; Imperial College London | en |
| local.identifier.doi | 10.1039/a900257j | en |
| local.identifier.pure | 3a4065a0-d1e4-4b7a-a30a-e3e006bffe94 | en |
| local.identifier.url | https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000079097200026&DestLinkType=FullRecord&DestApp=WOS_CPL | en |
| local.type.status | Published | en |