Phospha-alkyne hydro-osmiation:: synthesis of [Os{κ&lt;SUP&gt;1&lt;/SUP&gt;&lt;i&gt;P&lt;/i&gt;,κ&lt;SUP&gt;1&lt;/SUP&gt;&lt;i&gt;P&lt;/i&gt;′-P=CRP(=CHR)}Cl(CO)(PPh&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;](R = CMe&lt;sub&gt;3&lt;/sub&gt;)

Hill, AF; Jones, C; Wilton-Ely, JDET

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Phospha-alkyne hydro-osmiation:: synthesis of [Os{κ1P,κ1P′-P=CRP(=CHR)}Cl(CO)(PPh3)2](R = CMe3)

Date

1999-03-07

Authors

Hill, AF

Jones, C

Wilton-Ely, JDET

Abstract

The reaction of [OsHCl(CO)(PPh3)(2)(BTD)] (BTD = 2,1,3-benzothiadiazole) with P=CCMe3 provides the novel complex [Os{kappa(1)P,kappa(1)P'-P=CRP(=CHR)Cl(CO)(PPh3)(2)] (R = CMe3) which features both phospha-alkenyl and phosphaalkene donors within the same metallacycle.

Keywords

X-ray structure, Crystal-structure, Complexes, Ruthenium(ii)

URI

https://hdl.handle.net/1885/733809897

Collections

ANU Research Publications

Source

Chemical Communications

Type

Commentary

Entity type

Publication

DOI

10.1039/a900257j

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Phospha-alkyne hydro-osmiation:: synthesis of [Os{κ<SUP>1</SUP><i>P</i>,κ<SUP>1</SUP><i>P</i>′-P=CRP(=CHR)}Cl(CO)(PPh<sub>3</sub>)<sub>2</sub>](R = CMe<sub>3</sub>)

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Phospha-alkyne hydro-osmiation:: synthesis of [Os{κ&lt;SUP&gt;1&lt;/SUP&gt;&lt;i&gt;P&lt;/i&gt;,κ&lt;SUP&gt;1&lt;/SUP&gt;&lt;i&gt;P&lt;/i&gt;′-P=CRP(=CHR)}Cl(CO)(PPh&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;](R = CMe&lt;sub&gt;3&lt;/sub&gt;)

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Phospha-alkyne hydro-osmiation:: synthesis of [Os{κ<SUP>1</SUP><i>P</i>,κ<SUP>1</SUP><i>P</i>′-P=CRP(=CHR)}Cl(CO)(PPh<sub>3</sub>)<sub>2</sub>](R = CMe<sub>3</sub>)