B(3,4,5-F<sub>3</sub>H<sub>2</sub>C<sub>6</sub>)<sub>3</sub> Lewis acid-catalysed C3-allylation of indoles

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dc.contributor.authorAlotaibi, Nusaybahen
dc.contributor.authorBabaahmadi, Rasoolen
dc.contributor.authorPramanik, Milanen
dc.contributor.authorKaehler, Tanjaen
dc.contributor.authorDasgupta, Ayanen
dc.contributor.authorRichards, Emmaen
dc.contributor.authorAriafard, Alirezaen
dc.contributor.authorWirth, Thomasen
dc.contributor.authorMelen, Rebecca L.en
dc.date.accessioned2025-12-18T07:40:54Z
dc.date.available2025-12-18T07:40:54Z
dc.date.issued2023-04-11en
dc.description.abstractHerein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.en
dc.description.sponsorshipR.B. would like to thank the Royal Society for a Newton International Fellowship (NIF\R1\211330). A.D., E.R., and R.L.M. thank the Leverhulme Trust (RPG-2020-016)., and M.P.T.K. and R.L.M. thank the EPSRC (EP/R026912/1) for funding. R.B. and A.A. also thank the Australian National Computational Infrastructure Digital Research Services, IT Services at the University of Tasmania for the generous allocation of computing time. N.A. also acknowledges support from the Saudi Ministry of Education and the King Faisal University, Saudi Arabia. Information about the data that underpins the results presented in this article can be found in the Cardiff University data catalogue at http://doi.org/10.17035/d.2023.0252049034 . en
dc.description.statusPeer-revieweden
dc.format.extent5en
dc.identifier.issn1477-9226en
dc.identifier.otherPubMed:37063050en
dc.identifier.otherORCID:/0000-0003-2383-6380/work/198105694en
dc.identifier.scopus85153532409en
dc.identifier.urihttps://hdl.handle.net/1885/733796615
dc.language.isoenen
dc.provenanceThis article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.rights © 2023 The Author(s)en
dc.sourceDalton Transactionsen
dc.titleB(3,4,5-F<sub>3</sub>H<sub>2</sub>C<sub>6</sub>)<sub>3</sub> Lewis acid-catalysed C3-allylation of indolesen
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.lastpage5043en
local.bibliographicCitation.startpage5039en
local.contributor.affiliationAlotaibi, Nusaybah; Cardiff Universityen
local.contributor.affiliationBabaahmadi, Rasool; Cardiff Universityen
local.contributor.affiliationPramanik, Milan; Cardiff Universityen
local.contributor.affiliationKaehler, Tanja; Cardiff Universityen
local.contributor.affiliationDasgupta, Ayan; Cardiff Universityen
local.contributor.affiliationRichards, Emma; Cardiff Universityen
local.contributor.affiliationAriafard, Alireza; University of Tasmaniaen
local.contributor.affiliationWirth, Thomas; Cardiff Universityen
local.contributor.affiliationMelen, Rebecca L.; Cardiff Universityen
local.identifier.citationvolume52en
local.identifier.doi10.1039/d3dt00745fen
local.identifier.purea7b7f0a5-b2b9-438b-9633-d1d5229537deen
local.identifier.urlhttps://www.scopus.com/pages/publications/85153532409en
local.type.statusPublisheden

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