B(3,4,5-F3H2C6)3 Lewis acid-catalysed C3-allylation of indoles
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Alotaibi, Nusaybah
Babaahmadi, Rasool
Pramanik, Milan
Kaehler, Tanja
Dasgupta, Ayan
Richards, Emma
Ariafard, Alireza
Wirth, Thomas
Melen, Rebecca L.
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Herein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
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Dalton Transactions
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