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B(3,4,5-F<sub>3</sub>H<sub>2</sub>C<sub>6</sub>)<sub>3</sub> Lewis acid-catalysed C3-allylation of indoles

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Date

2023-04-11

Authors

Alotaibi, Nusaybah
Babaahmadi, Rasool
Pramanik, Milan
Kaehler, Tanja
Dasgupta, Ayan
Richards, Emma
Ariafard, Alireza
Wirth, Thomas
Melen, Rebecca L.

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Abstract

Herein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.

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https://hdl.handle.net/1885/733796615

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ANU Research Publications

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Dalton Transactions

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Journal article

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DOI

10.1039/d3dt00745f

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