Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: New insights into the reaction mechanism
| dc.contributor.author | Ghari, Hossein | en |
| dc.contributor.author | Li, Yifan | en |
| dc.contributor.author | Roohzadeh, Roohollah | en |
| dc.contributor.author | Caramenti, Paola | en |
| dc.contributor.author | Waser, Jerome | en |
| dc.contributor.author | Ariafard, Alireza | en |
| dc.date.accessioned | 2026-01-01T13:41:58Z | |
| dc.date.available | 2026-01-01T13:41:58Z | |
| dc.date.issued | 2017 | en |
| dc.description.abstract | Gold-catalyzed domino processes constitute a useful alternative to C-H functionalization for the synthesis of functionalized (hetero)arenes. Herein, we report computational studies on the gold-catalyzed cyclization alkynylation of keto-allenes with ethynylbenziodoxole (EBX) reagents, which identified a gold(i) picolinate complex as the active catalyst, giving the first mechanistic insights into this transformation. | en |
| dc.description.sponsorship | We thank the Swiss National Science Foundation (Grant No. 200021_159920) for financial support. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 6 | en |
| dc.identifier.issn | 1477-9226 | en |
| dc.identifier.other | PubMed:28875203 | en |
| dc.identifier.other | ORCID:/0000-0003-2383-6380/work/163628644 | en |
| dc.identifier.scopus | 85029634278 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733800742 | |
| dc.language.iso | en | en |
| dc.rights | Publisher Copyright: © 2017 The Royal Society of Chemistry. | en |
| dc.source | Dalton Transactions | en |
| dc.title | Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: New insights into the reaction mechanism | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 12262 | en |
| local.bibliographicCitation.startpage | 12257 | en |
| local.contributor.affiliation | Ghari, Hossein; Islamic Azad University | en |
| local.contributor.affiliation | Li, Yifan; Swiss Federal Institute of Technology Lausanne | en |
| local.contributor.affiliation | Roohzadeh, Roohollah; Islamic Azad University | en |
| local.contributor.affiliation | Caramenti, Paola; Swiss Federal Institute of Technology Lausanne | en |
| local.contributor.affiliation | Waser, Jerome; Swiss Federal Institute of Technology Lausanne | en |
| local.contributor.affiliation | Ariafard, Alireza; Department of Chemistry | en |
| local.identifier.citationvolume | 46 | en |
| local.identifier.doi | 10.1039/c7dt03154h | en |
| local.identifier.pure | 7f888cb3-4840-4157-9b9e-3074ae9eb27c | en |
| local.identifier.url | https://www.scopus.com/pages/publications/85029634278 | en |
| local.type.status | Published | en |