Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents
Date
Authors
Ghari, Hossein
Li, Yifan
Roohzadeh, Roohollah
Caramenti, Paola
Waser, Jerome
Ariafard, Alireza
Journal Title
Journal ISSN
Volume Title
Publisher
Access Statement
Abstract
Gold-catalyzed domino processes constitute a useful alternative to C-H functionalization for the synthesis of functionalized (hetero)arenes. Herein, we report computational studies on the gold-catalyzed cyclization alkynylation of keto-allenes with ethynylbenziodoxole (EBX) reagents, which identified a gold(i) picolinate complex as the active catalyst, giving the first mechanistic insights into this transformation.
Description
Keywords
Citation
Collections
Source
Dalton Transactions
Type
Book Title
Entity type
Publication