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Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands

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dc.contributor.authorKirk, Ryan M.en
dc.contributor.authorHill, Anthony F.en
dc.date.accessioned2025-12-16T12:40:31Z
dc.date.available2025-12-16T12:40:31Z
dc.date.issued2025en
dc.description.abstractPhosphinoisocyanide complexes undergo facile [3 + 2] cycloaddition reactions with activated alkynes to afford the first azaphospholylidene complexes which are rare examples of N,P-heterocyclic carbenes (NPHC). In addition to quantifying the donor/acceptor properties of this new class of carbene, their transmetalation reactions are also described.en
dc.description.sponsorshipThe authors gratefully acknowledge the Australian Research Council (DP230100215) for funding.en
dc.description.statusPeer-revieweden
dc.format.extent6en
dc.identifier.issn1433-7851en
dc.identifier.otherWOS:001493597300001en
dc.identifier.otherORCID:/0000-0003-2167-0604/work/186563762en
dc.identifier.scopus105006610923en
dc.identifier.urihttps://hdl.handle.net/1885/733795459
dc.language.isoenen
dc.provenanceThis is an open access article underthe terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in anymedium, provided the original work is properly cited, the use isnon-commercial and no modifications or adaptations are madeen
dc.rights© 2025 The Author(s). Angewandte Chemie International Edition published by Wiley-VCH GmbH.en
dc.sourceAngewandte Chemie - International Editionen
dc.subjectCycloadditionen
dc.subjectHeterocyclic carbeneen
dc.subjectIsocyanideen
dc.subjectPhosphorus heterocyclesen
dc.subjectTransmetalationen
dc.titlePhosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligandsen
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.lastpage6en
local.bibliographicCitation.startpage1en
local.contributor.affiliationKirk, Ryan M.; Research School of Chemistry, ANU College of Science and Medicine, The Australian National Universityen
local.contributor.affiliationHill, Anthony F.; Research School of Chemistry, ANU College of Science and Medicine, The Australian National Universityen
local.identifier.citationvolume64en
local.identifier.doi10.1002/anie.202504620en
local.identifier.pure0cfb3849-9f22-49e2-9999-dca8f9dde652en
local.identifier.urlhttps://www.scopus.com/pages/publications/105006610923en
local.type.statusPublisheden

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