Phosphinoisocyanide/Alkyne Cycloaddition
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Kirk, Ryan M.
Hill, Anthony F.
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Abstract
Phosphinoisocyanide complexes undergo facile [3 + 2] cycloaddition reactions with activated alkynes to afford the first azaphospholylidene complexes which are rare examples of N,P-heterocyclic carbenes (NPHC). In addition to quantifying the donor/acceptor properties of this new class of carbene, their transmetalation reactions are also described.
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Angewandte Chemie - International Edition
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