Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands

Thumbnail Image

Date

2025

Authors

Kirk, Ryan M.
Hill, Anthony F.

Journal Title

Journal ISSN

Volume Title

Publisher

Access Statement

Research Projects

Organizational Units

Journal Issue

Abstract

Phosphinoisocyanide complexes undergo facile [3 + 2] cycloaddition reactions with activated alkynes to afford the first azaphospholylidene complexes which are rare examples of N,P-heterocyclic carbenes (NPHC). In addition to quantifying the donor/acceptor properties of this new class of carbene, their transmetalation reactions are also described.

Description

Keywords

Cycloaddition, Heterocyclic carbene, Isocyanide, Phosphorus heterocycles, Transmetalation

Citation

URI

https://hdl.handle.net/1885/733795459

Collections

ANU Research Publications

Source

Angewandte Chemie - International Edition

Type

Journal article

Book Title

Entity type

Publication

Access Statement

License Rights

DOI

10.1002/anie.202504620

Restricted until

Downloads

File
Description
Angew_Chem_Int_Ed_-_2025_-_Kirk_-_Phosphinoisocyanide_Alkyne_Cycloaddition_Generation_of_Azaphospholylidene_NPHC_Ligands.pdf (1.25 MB)

DSpace software copyright © 2002-2026 LYRASIS