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Stereocontrolled aldol additions to α-methylene-β-alkoxy aldehydes: Application to the synthesis of a C<sub>13</sub>C<sub>25</sub> segment of bafilomycin A<sub>1</sub>

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Date

1995-01-02

Authors

Paterson, Ian
Bower, Shelley
McLeod, Malcolm D.

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Research Projects

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Abstract

A boron-mediated, syn-aldol coupling between ethyl ketone 8 and aldehyde 9, followed by directed hydrogenation at C16 and acetonide hydrolysis, gives the C13C25 segment 6 of bafilomycin A1.

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https://hdl.handle.net/1885/733803918

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ANU Research Publications

Source

Tetrahedron Letters

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Journal article

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Publication

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DOI

10.1016/0040-4039(94)02205-P

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