Formation of (Diphenylphosphino)naphthalenes by Double Insertion of (Alkynyl)diphenylphosphines into Nickel(0)-Benzyne Complexes

Bennett, Martin; Cobley, Christopher; Rae, A David; Wenger, Eric; Willis, Anthony

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Formation of (Diphenylphosphino)naphthalenes by Double Insertion of (Alkynyl)diphenylphosphines into Nickel(0)-Benzyne Complexes

Date

2000

Authors

Bennett, Martin

Cobley, Christopher

Rae, A David

Wenger, Eric

Willis, Anthony

Publisher

American Chemical Society

Abstract

(Alkynyl)diphenylphosphines Ph2PC≡CR (R = H, Me, Ph, PPh2) undergo double insertion into the nickel(0)-benzyne bond of the complexes [Ni{(1,2-η)-4,5-X2C6H2}(PEt 3)2] (X = H (1a), F (1b)) to give mixtures of nickel(O) complexes containing (diphenylphosp

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http://hdl.handle.net/1885/90194

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ANU Research Publications

Source

Organometallics

Type

Journal article

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2037-12-31

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Formation of (Diphenylphosphino)naphthalenes by Double Insertion of (Alkynyl)diphenylphosphines into Nickel(0)-Benzyne Complexes

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