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Organometallic macrocyclic chemistry. 8: an unusual metallacycle derived from phosphine-alkynyl thioether coupling

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Date

2010

Authors

Hill, Anthony
Niess, Barbara
Schultz, Madeleine
White, Andrew J P
Williams, David

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6 to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3) {κ4C,S,S′,S″-S(C≡CMe)C2H4SC2H4SC(PPh3)CMe}]PF6 arising from the activation of one alkynyl grou

Description

Keywords

Keywords: Alkynyl groups; Alkynyls; Macrocyclics; Metallacycles; Nucleophilic attack; Thioethers; Organometallics; Ruthenium compounds; Phosphorus compounds

Citation

URI

http://hdl.handle.net/1885/60920

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om100835r

Restricted until

2037-12-31

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01_Hill_Organometallic_macrocyclic_2010.pdf (862.24 KB)

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