Investigating the Stability of the Peroxide Bridge in  m -oxo and di- m -oxo manganese Clusters

Delfs, Christopher; Stranger, Robert

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Investigating the Stability of the Peroxide Bridge in m -oxo and di- m -oxo manganese Clusters

Date

2003

Authors

Delfs, Christopher

Stranger, Robert

Publisher

American Chemical Society

Abstract

The stability of the peroxide ligand bridging two manganese ions in the trinuclear oxomanganese complex [MnIII3(μ3-O2)(AcO) 2(dien)3]2+, one of only two structurally characterized Mn clusters possessing a μ1,2-peroxo bridge, has been investigated using