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Synthesis and X-ray structure of a heterovalent, cycloaurated pentafluorophenylgold(I)/pentafluorophenylgold(III) complex.

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Date

2002

Authors

Bennett, Martin
Bhargava, Suresh Kumar
Mohr, Fabian
Welling, Lee
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

CSIRO Publishing

Abstract

The heterovalentgold(I)/gold(III)complex [(C6F 5)AuI(μ-2-Ph2PC6H 3-6-Me)AuIII(C6F5)(η 2-(6-MeC6H3-2-PPh2)}] has been prepared and structurally characterized by X-ray crystallography. It shows square planar stereochemistry at AuIII incorporating a four-m

Description

Keywords

Keywords: Chemical bonds; Complexation; Crystal structure; Derivatives; Filtration; Fluorine containing polymers; Gold; Isomerization; Negative ions; Nuclear magnetic resonance spectroscopy; Organometallics; Oxidation; Stereochemistry; X ray crystallography; Four-m

Citation

URI

http://hdl.handle.net/1885/72526

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1071/CH02034

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