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Radio labelling of the gibberellin plant growth inhibitor 16,17-dihydro-GA 5

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dc.contributor.authorMorrison (previously Beck), Ellen
dc.contributor.authorTwitchin, Bruce
dc.contributor.authorMander, Lewis
dc.date.accessioned2015-12-13T22:39:41Z
dc.date.available2015-12-13T22:39:41Z
dc.date.issued2004
dc.date.updated2015-12-11T09:51:43Z
dc.description.abstractAn improved five-step procedure has been developed for the synthesis of the gibberellin plant growth inhibitor 16,17-dihydro-GA5 from gibberellic acid. The 3-13C and 3-14C derivatives of this material have also been prepared by excising C-3 from the carbon skeleton (ozonolysis of a Δ2-alkene derivative and subsequent retro-Claisen reaction) and then reassembling the A-ring by means of an intramolecular aldol reaction.
dc.identifier.issn0008-4042
dc.identifier.urihttp://hdl.handle.net/1885/77886
dc.publisherNRC Research Press
dc.sourceCanadian Journal of Chemistry
dc.subjectKeywords: Carbon; Carboxylic acids; Derivatives; Labeling; Olefins; Ozonization; Synthesis (chemical); Aldol reactions; Carbon skeleton; Plant growth inhibitors; Retro-Claisen reaction; Plants (botany); carbon 13; carbon 14; gibberellic acid; gibberellin; phytohorm Degradation; Gibberellin; Growth inhibitor; Radio labelling; Wittig reaction
dc.titleRadio labelling of the gibberellin plant growth inhibitor 16,17-dihydro-GA 5
dc.typeJournal article
local.bibliographicCitation.issue2
local.bibliographicCitation.lastpage300
local.bibliographicCitation.startpage293
local.contributor.affiliationMorrison (previously Beck), Ellen, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationTwitchin, Bruce, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMander, Lewis, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidMorrison (previously Beck), Ellen, u4005777
local.contributor.authoruidTwitchin, Bruce, u7100542
local.contributor.authoruidMander, Lewis, u7500768
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub6631
local.identifier.citationvolume82
local.identifier.doi10.1139/v03-202
local.identifier.scopusID2-s2.0-2342564422
local.type.statusPublished Version

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