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Pyridine-2,6-bis(thioether) (SNS) complexes of ruthenium as catalysts for transfer hydrogenation

Date

Authors

Page, Michael

Wagler, Jorg

Messerle, Barbara Ann

Publisher

American Chemical Society

Abstract

Coordination of the pincer ligand 2,6-bis(tert-butylthiomethyl)pyridine (SNStBu) to Ru(PPh3)3Cl2 and Ru(MeCN)4Cl2 led to the isolation of the complexes Ru(SNStBu)Cl2(PPh3) (1) and Ru(SNStBu)Cl2(MeCN) (4), respectively. Substitution of one chloride ligand

Keywords

Keywords: Acetophenones; Chloride ligands; Dicationic complexes; Pincer ligands; Salt metathesis; Steric congestion; Thioethers; Transfer hydrogenations; Turnover frequency; Acetonitrile; Catalyst activity; Chlorine compounds; Hydrogenation; Ketones; Ligands; Pyrid

URI

http://hdl.handle.net/1885/60633

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om1005319

Restricted until

2037-12-31

Downloads

File

Description

01_Page_Pyridine-2,6-bis(thioether)_2010.pdf (1.07 MB)

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