Synthesis of a D-ring Isomer of Galanthamine via a Radical-Based Smiles Rearrangement Reaction
Date
2014
Authors
Lan, Ping
Jackson, Colin
Banwell, Martin
Willis, Anthony
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American Chemical Society
Abstract
The 1,9-ethanoiminomethano-bridged tetrahydrodibenzo[b,d]-furan 2, a non-natural isomer of the alkaloid (-)-galanthamine (1) varying in the manner in which the D-ring is annulated to the ABC-core, has been prepared in racemic form. The synthetic sequence
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Journal of Organic Chemistry
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Journal article
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2037-12-31
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