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The frequently overlooked importance of solvent in free radical syntheses

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dc.contributor.authorLitwinienko, Grzegorz
dc.contributor.authorBeckwith, Athelstan (Athel)
dc.contributor.authorIngold, Keith U
dc.date.accessioned2015-12-10T22:45:42Z
dc.date.issued2011
dc.date.updated2015-12-09T11:22:50Z
dc.description.abstractThis tutorial review is designed to dispel the myth, still believed by many synthetic organic chemists, that radical-based syntheses are free from significant solvent effects. However, many synthetically valuable radical reactions do exhibit large kinetic solvent effects. It is therefore important to select the solvent for any proposed radical synthesis with considerable care if good product yields are to be achieved.
dc.identifier.issn0306-0012
dc.identifier.urihttp://hdl.handle.net/1885/58610
dc.publisherRoyal Society of Chemistry
dc.sourceChemical Society Reviews
dc.titleThe frequently overlooked importance of solvent in free radical syntheses
dc.typeJournal article
local.bibliographicCitation.issue5
local.bibliographicCitation.lastpage2163
local.bibliographicCitation.startpage2175
local.contributor.affiliationLitwinienko, Grzegorz, University of Warsaw
local.contributor.affiliationBeckwith, Athelstan (Athel), College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationIngold, Keith U, National Research Council of Canada
local.contributor.authoruidBeckwith, Athelstan (Athel), u810237
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4005981xPUB450
local.identifier.citationvolume40
local.identifier.doi10.1039/c1cs15007c
local.identifier.scopusID2-s2.0-79954574118
local.type.statusPublished Version

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