Organometallic complexes for nonlinear optics Part 21. Syntheses and quadratic hyperpolarizabilities of alkynyl complexes containing optically active 1,2-bis(methylphenylphosphino)benzene ligands
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McDonagh, Andrew
Cifuentes, Marie
Houbrechts, Stephan
Maes, Joachim
Persoons, Andre Pierre
Samoc, Marek
Luther-Davies, Barry
Humphrey, Mark
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Elsevier
Abstract
The preparation of the chloro complex trans-[FeCl2{(R,R)-diph}2] (1) and the alkynyl complexes trans-[M(4-C≡CC6H4R)Cl{(R,R)-diph}2] [M = Fe, R = NO2 (2); M = Ru, R = H (4), NO2 (5), (E)-CH=CH-4-C6H4NO2 (6); M = Os, R = NO2 (7)], incorporating the optica
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Journal of Organometallic Chemistry
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2037-12-31