Organometallic complexes for nonlinear optics Part 21. Syntheses and quadratic hyperpolarizabilities of alkynyl complexes containing optically active 1,2-bis(methylphenylphosphino)benzene ligands

Date

2000

Authors

McDonagh, Andrew
Cifuentes, Marie
Houbrechts, Stephan
Maes, Joachim
Persoons, Andre Pierre
Samoc, Marek
Luther-Davies, Barry
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

The preparation of the chloro complex trans-[FeCl2{(R,R)-diph}2] (1) and the alkynyl complexes trans-[M(4-C≡CC6H4R)Cl{(R,R)-diph}2] [M = Fe, R = NO2 (2); M = Ru, R = H (4), NO2 (5), (E)-CH=CH-4-C6H4NO2 (6); M = Os, R = NO2 (7)], incorporating the optica

Description

Keywords

Keywords: Alkynyl; Chiral diphosphine; Cyclic voltammetry; Iron; Nonlinear optics; Osmium; Quadratic hyperpolarizabilities; Ruthenium

Citation

Source

Journal of Organometallic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/S0022-328X(00)00420-4

Restricted until

2037-12-31