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Chemoenzymatic and enantiodivergent routes to highly functionalised steroidal nuclei

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Date

1999

Authors

Banwell, Martin
Hockless, David
Holman, Jeffrey
Longmore, Robert
McRae, Kenneth
Pham, Ha

Journal Title

Journal ISSN

Volume Title

Publisher

Georg Thieme Verlag

Abstract

The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).

Description

Keywords

Keywords: catechol derivative; steroid; article; enantiomer; reaction analysis; stereochemistry; steroidogenesis Anionic oxy-Cope rearrangement; Diels-Alder cycloaddition; Enantiodivergent synthesis; Steroids

Citation

URI

http://hdl.handle.net/1885/93743

Collections

ANU Research Publications

Source

Synlett

Type

Journal article

Book Title

Entity type

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DOI

Restricted until

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