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Reactions of Co(III)-coordinated ornithine: towards inhibitors of the polyamine biosynthetic pathway

Date

Authors

Clarkson, Andrea J

Blackman, Allan G.

Clark, Charles R

Sargeson, Alan

Publisher

CSIRO Publishing

Abstract

Treatment of the complex ,Δ-Λ[Co(en)2(S-ornithineH- κ2N,O)](CF3SO3)3 with SOCl2 in DMF gives a mixture of the expected imino complex [Co(en)2(2-iminoornithineH-2N,O)]3+ and the amidine complex [Co(en)2(5-{[(1E)-(dimethylamino)methylene]amino}-2- iminop

Keywords

Keywords: Alkaline solutions; Biosynthetic pathway; Nitromethane; Polyamines; Suicide inhibitor; Vilsmeier reagent; X ray crystal structures; Amination; Amines; Cobalt; Coordination reactions; Cobalt compounds

URI

http://hdl.handle.net/1885/55700

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

DOI

10.1071/CH09315

Restricted until

2037-12-31

Downloads

File

Description

01_Clarkson_Reactions_of_2009.pdf (335.2 KB)