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Computational evaluation of the sulfonyl radical as a universal leaving group for RAFT polymerisation

Date

Authors

Gryn'ova, Ganna

Guliashvili, Tamaz

Matyjaszewski, Krzysztof

Coote, Michelle

Publisher

CSIRO Publishing

Abstract

The present study investigates the performance of the sulfonyl radical, i.e. •SO2Ph, as a universal leaving group in reversible addition-fragmentation chain-transfer (RAFT) polymerisation. The sulfonyl radical is widely used as a radical initiator and h

Keywords

Keywords: Computational evaluation; Computational methodology; Experimental conditions; Functionalisation; Leaving groups; Radical initiators; Reversible addition fragmentation chain transfer; Synthetic routes; Free radical polymerization; Sulfur dioxide; Polymers

URI

http://hdl.handle.net/1885/20269

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

DOI

10.1071/CH12452

Restricted until

2037-12-31

Downloads

File

Description

01_Gryn'ova_Computational_evaluation_of_2013.pdf (162.86 KB)