A cyclodextrin molecular reactor for the regioselective synthesis of 1,5-disubstituted-1,2,3-triazoles
Date
2005
Authors
Barr, Lorna
Lincoln, Stephen F
Easton, Christopher
Journal Title
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Volume Title
Publisher
Taylor & Francis Group
Abstract
6A-Deoxy-6A-propynamido-β-cyclodextrin reacts with 4-tert-butylphenyl azide in aqueous solution, to form the 5-(aminocarbonyl)-substituted triazole in preference to the 4-(aminocarbonyl)- substituted analogue, in a ratio of 25:1. The cyclodextrin moiety
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Keywords
Keywords: Cycloadditions; Cyclodextrins; Molecular reactors; Regio selectivity; Templates; Triazoles
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Source
Supramolecular Chemistry
Type
Journal article
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2037-12-31
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