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ortho -Metallated complexes of platinum(II) and diplatinum(I) containing the carbanions (2-diphenylphosphino)phenyl and (2-diphenylphosphino)- n -tolyl ( n = 5, 6)

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Date

2007

Authors

Bennett, Martin
Bhargava, Suresh Kumar
Messelhauser, Johannes
Priver, Steven H
Welling, Lee
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

When the ortho-metallated complexes cis-[Pt(κ2-C 6H3-5-R-2-PPh2)2] (R = H 1, Me 2) are either heated in toluene or treated with CO at room temperature, one of the four-membered chelate rings is opened irreversibly to give dinuclear isomers [Pt2(κ2-C6H3-

Description

Keywords

Keywords: Chemical bonds; Ligands; Platinum; Protonation; Toluene; X ray diffraction; Bridging carbanion; Chelate rings; Electrophiles; Metal complexes

Citation

URI

http://hdl.handle.net/1885/29258

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/b702808c

Restricted until

2037-12-31

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01_Bennett_ortho_-Metallated_complexes_of_2007.pdf (340.63 KB)

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