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Spectrally resolved microprobe cathodoluminescence of intergrowth Bi₅ˍₓLaₓTiNbWO₁₅ ferroelectrics

dc.contributor.authorGe, Wanyin
dc.contributor.authorZhu, Wenliang
dc.contributor.authorHigashino, Masayuki
dc.contributor.authorLi, Yongxiang
dc.contributor.authorYi, Zhiguo
dc.contributor.authorPezzotti, Giuseppe
dc.date.accessioned2015-11-26T04:15:13Z
dc.date.available2015-11-26T04:15:13Z
dc.date.issued2007-10-05
dc.description.abstractSpectrally resolved cathodoluminescence measurements of Bi₅ˍₓLaₓTiNbWO₁₅(x=0–1.50) ceramics at room temperature showed three distinct luminescence bands located at about 380, 502, and 660nm, respectively, which were tentatively assigned to F+ center, oxygen vacancy-related defect and octahedron structure-related luminescence center, respectively. These assignments could be made in light of electron irradiation experiments with different exposure times. Bands related to oxygen vacancies were clearly enhanced by lanthanum doping, indicating that charge compensation occurred by the substitution of Bi for La3+ in perovskitelike structured intergrowth ferroelectrics. We observed that, for contents of La³⁺ x>0.75, La³⁺ ions entered the [Bi₂O₂]²⁺ layer according to a doping mechanism which is briefly discussed in this letter.en_AU
dc.description.sponsorshipThis work was supported by the Ministry of Sciences and Technology of China through 973-project 2002CB613307 and National Natural Science Foundation of China NSFC No. 50572113.en_AU
dc.identifier.issn0021-8979en_AU
dc.identifier.urihttp://hdl.handle.net/1885/16837
dc.publisherAmerican Institute of Physics (AIP)en_AU
dc.rightshttp://www.sherpa.ac.uk/romeo/issn/0021-8979..."Publishers version/PDF may be used on author's personal website, institutional website or institutional repository" from SHERPA/RoMEO site (as at 26/11/15). Copyright 2007 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Applied Physics and may be found at https://doi.org/10.1063/1.2767857en_AU
dc.sourceJournal of Applied Physicsen_AU
dc.titleSpectrally resolved microprobe cathodoluminescence of intergrowth Bi₅ˍₓLaₓTiNbWO₁₅ ferroelectricsen_AU
dc.typeJournal articleen_AU
local.bibliographicCitation.issue7en_AU
local.bibliographicCitation.startpage076106en_AU
local.contributor.affiliationGe, Wanyin, Kyoto Institute of Technology, Japanen_AU
local.contributor.affiliationZhu, Wenliang, Kyoto Institute of Technology, Japanen_AU
local.contributor.affiliationHigashino, Masayuki, Kyoto Institute of Technology, Japanen_AU
local.contributor.affiliationLi, Yongxiang, Shanghai Institute of Ceramics, Chinaen_AU
local.contributor.affiliationYi, Zhiguo, College of Physical and Mathematical Sciences, CPMS Research School of Chemistry, RSC General, The Australian National Universityen_AU
local.contributor.affiliationPezzotti, Giuseppe, Kyoto Institute of Technology, Japanen_AU
local.contributor.authoruidu4610857en_AU
local.description.notesImported from ARIES. At the time of publication the author Z. G. Yi was affiliated with State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Chinaen_AU
local.identifier.absfor030206en_AU
local.identifier.ariespublicationu4217927xPUB490en_AU
local.identifier.citationvolume102en_AU
local.identifier.doi10.1063/1.2767857en_AU
local.publisher.urlhttps://www.aip.org/en_AU
local.type.statusPublished Versionen_AU

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