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Insertions of unsymmetric alkynes into the metal-carbon bonds of nickelacycles: What determines the regiochemistry?

Date

Authors

Bennett, Martin

Macgregor, Stuart A

Wenger, Eric

Publisher

Wiley-VCH Verlag GMBH

Abstract

Although the insertion of alkynes into transition-metal - carbon bonds plays an important role in synthesis, the regioselectivities observed with unsymmetric alkynes have usually been interpreted on the basis of steric effects. In this perspective paper,

Keywords

Keywords: Chemical bonds; Nickel; Transition metals; Alkanyes; Synthesis (chemical); carbon; metal complex; nickel complex; organometallic compound; palladium complex; article; chemical reaction; chemical structure; complex formation; isomerism; kinetics; stereoche

URI

http://hdl.handle.net/1885/93308

Collections

ANU Research Publications

Source

Helvetica Chimica Acta

Type

Journal article

DOI

10.1002/1522-2675(20011017)84:10<3084::AID-HLCA3084>3.0.CO;2-H

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