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Are pi-ligand exchange reactions of thiirenium and thiiranium ions feasible? An ab initio investigation

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Date

1999

Authors

Solling, Theis
Wild, Stanley (Bruce)
Radom, Leo

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

Ab initio calculations at the G2 level have been employed to investigate the hitherto unobserved π-ligand exchange reactions of thiirenium and thiiranium ions. Two pathways for exchange and one pathway for insertion are presented. The lower energy exchan

Description

Keywords

Keywords: article; calculation; chemical analysis; chemical reaction; chemical structure; structure analysis Ab initio calculations; Exchage reactions; Insertions; Pi interactions; Sulfur heterocycles

Citation

URI

http://hdl.handle.net/1885/93782

Collections

ANU Research Publications

Source

Chemistry, A European Journal

Type

Journal article

Book Title

Entity type

Access Statement

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DOI

Restricted until

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