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Stoichiometric and catalytic demercuration of bis(tricarbido)mercurials: The first dimetallaoctatetraynes

Date

Authors

Dewhurst, Rian

Hill, Anthony

Willis, Anthony

Publisher

American Chemical Society

Abstract

Treating the complexes [Hg{C≡CC≡W-(CO)2L} 2] (L = HB(pz)3 (1a), HB(pz′)3 (1b);pz = pyrazol-1-yl; pz′ = 3,5-dimethylpyrazol-1-yl) with 1 equiv of cis-[PtCl2(PPh3)2] or a catalytic amount of trans-[RhCl(CO)-(PPh3)2] provides the bimetallic complexes

Keywords

Keywords: Alcohols; Catalysis; Chemical bonds; Crystal structure; Molecular structure; Nuclear magnetic resonance; Stoichiometry; Synthesis (chemical); Transition metals; Bis(tricarbido)mercurials; Catalytic demercuration; Dimetallaoctatetraynes; Ligands; Mercury c

URI

http://hdl.handle.net/1885/81606

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om058011u

Restricted until

2037-12-31

Downloads

File

Description

01_Dewhurst_Stoichiometric_and_catalytic_2005.pdf (111.22 KB)

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