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A chemoenzymatic synthesis of (-)-hirsutene from toluene

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Date

2002

Authors

Banwell, Martin
Edwards, Alison
Harfoot, Gwion
Jolliffe, Katrina

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The enantiomerically pure cis-1,2-diol 2, which is obtained by microbial oxidation of toluene, has been converted, via a sequence of reactions including high-pressure promoted Diels-Alder cycloaddition and oxa-di-π-methane rearrangement steps, into the t

Description

Keywords

Keywords: Acetone; Addition reactions; Alcohols; Irradiation; Methane; Nuclear magnetic resonance spectroscopy; Oxidation; Structure (composition); Synthesis (chemical); X ray analysis; Chemoenzymatic synthesis; Diels-alder cycloaddition; Hirsutene; Microbial oxida

Citation

URI

http://hdl.handle.net/1885/72390

Collections

ANU Research Publications

Source

Journal of the Chemical Society, Perkin Transactions 1

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until

2037-12-31

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