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Facile generation of Lithiocarbyne Complexes: [M(=CLi)(CO) 2 {HB(pzMe 2 ) 3 }] (M = Mo, W; pz = Pyrazol-1-yl)

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dc.contributor.authorCordiner, Richard
dc.contributor.authorHill, Anthony
dc.contributor.authorWagler, Jorg
dc.date.accessioned2015-12-10T22:27:22Z
dc.date.issued2008
dc.date.updated2016-02-24T10:42:22Z
dc.description.abstractThe reactions of [M(≡CX)(CO)2{HB(pzMe2) 3}] (M = Mo, W; X = Cl, Br; pz = pyrazol-1-yl) with "BuLi provide the lithiocarbyne complexes [M(≡CLi)(CO)2{HB(pzMe 2)3}], which react with a range of electrophiles to provide variously functionalized carbyne an
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/54174
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Chlorine compounds; Hysteresis motors; Iron compounds; Molybdenum; Tellurium compounds; Tungsten compounds; Carbyne; Electrophiles; Functionalized; Molybdenum compounds
dc.titleFacile generation of Lithiocarbyne Complexes: [M(=CLi)(CO) 2 {HB(pzMe 2 ) 3 }] (M = Mo, W; pz = Pyrazol-1-yl)
dc.typeJournal article
local.bibliographicCitation.issue20
local.bibliographicCitation.lastpage5179
local.bibliographicCitation.startpage5177
local.contributor.affiliationCordiner, Richard, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWagler, Jorg, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidCordiner, Richard, u4364550
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidWagler, Jorg, v006707
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB293
local.identifier.citationvolume27
local.identifier.doi10.1021/om800733m
local.identifier.scopusID2-s2.0-55249089037
local.identifier.thomsonID000259988800002
local.type.statusPublished Version

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