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Dimetalla-heterocyclic carbenes: the interconversion of chalcocarbonyl and carbido ligands

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dc.contributor.authorBarnett, Harrison
dc.contributor.authorHill, Anthony
dc.date.accessioned2020-12-13T23:02:34Z
dc.date.issued2020-10-25
dc.description.abstractThe μ-carbido complexes [Rh2(μ-C)Cl2(PPh3)4] and [Rh2(μ-C)Cl2(dppm)2] cleave CS2 to afford the monothiocarbonyl complexes [RhCl(CS)(PPh3)2] and [Rh2(μ-CS)Cl2(dppm)2]. The latter reacts with dimethyl acetylenedicarboxylate (DMAD) to afford [Rh(μ-CS)(μ-DMAD)Cl2(dppm)2]. This complex is also formed from [Rh(μ-C)(μ-DMAD)Cl2(dppm)2] and sulfur. These strategies also afford the first rhodium selenocarbonyl complexes [Rh(μ-CSe)Cl2(dppm)2] and [Rh(μ-CSe)(μ-DMAD)Cl2(dppm)2].en_AU
dc.description.sponsorshipDP170102695 and DP190100723en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1364-548Xen_AU
dc.identifier.urihttp://hdl.handle.net/1885/216927
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18003..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020).en_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rights© 2020 Royal Society of Chemistryen_AU
dc.sourceChemical communicationsen_AU
dc.titleDimetalla-heterocyclic carbenes: the interconversion of chalcocarbonyl and carbido ligandsen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.issue83en_AU
local.bibliographicCitation.lastpage12596en_AU
local.bibliographicCitation.startpage12593en_AU
local.contributor.affiliationBarnett, H., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.affiliationHill, A., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.authoruidu4030185en_AU
local.identifier.citationvolume56en_AU
local.identifier.doi10.1039/d0cc05106cen_AU
local.identifier.essn1364-548Xen_AU
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/CCen_AU
local.type.statusAccepted Versionen_AU

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