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Photofragment emission yield spectroscopy of acetylene in the D̃ ¹Πu, Ẽ ¹A, and F̃¹Σu⁺ states by vacuum ultraviolet and infrared vacuum ultraviolet double-resonance laser excitations

dc.contributor.authorKono, Mitsuhiko
dc.contributor.authorHoshina, Kennosuke
dc.contributor.authorYamanouchi, Kaoru
dc.date.accessioned2015-10-21T00:28:46Z
dc.date.available2015-10-21T00:28:46Z
dc.date.issued2002-07-15
dc.date.updated2015-12-11T07:42:12Z
dc.description.abstractThe photodissociation process of Rydberg states of acetylene was investigated by vacuum ultraviolet and infrared vacuum ultraviolet double-resonance laser excitations. The high-resolving power of the method enabled to discuss absorption peak profiles characteristic of molecules which dissociate in an ultrashort time scale. The term values and homogeneous bandwidths of the vibrational levels in the three overlapping electronic states were determined with high precision from least squares fits to the observed peaks profiles broadened by a fast dissociation process.
dc.description.sponsorshipThe present work has been supported by the CREST (Core Research for Evolutionary Science and Technology) fund from Japan Science and Technology Corporation.en_AU
dc.identifier.issn0021-9606en_AU
dc.identifier.urihttp://hdl.handle.net/1885/15991
dc.publisherAmerican Institute of Physics (AIP)
dc.rightshttp://www.sherpa.ac.uk/romeo/issn/0021-9606..."Publishers version/PDF may be used on author's personal website, institutional website or institutional repository" from SHERPA/RoMEO site (as at 21/10/15). Copyright 2002 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in The Journal of Chemical Physics and may be found at https://doi.org/10.1063/1.1485064
dc.sourceThe Journal of Chemical Physics
dc.subjectKeywords: Acetylene; Bandwidth; Electron resonance; Electron transitions; Fluorescence; Photodissociation; Spectroscopic analysis; Ultraviolet radiation; Vacuum; Photofragment emission yield spectroscopy; Electron energy levels
dc.titlePhotofragment emission yield spectroscopy of acetylene in the D̃ ¹Πu, Ẽ ¹A, and F̃¹Σu⁺ states by vacuum ultraviolet and infrared vacuum ultraviolet double-resonance laser excitations
dc.typeJournal article
local.bibliographicCitation.issue3en_AU
local.bibliographicCitation.lastpage1046en_AU
local.bibliographicCitation.startpage1040en_AU
local.contributor.affiliationKono, Mitsuhiko, College of Physical and Mathematical Sciences, CPMS Research School of Physics and Engineering, Atomic and Molecular Physics Laboratories, The Australian National Universityen_AU
local.contributor.affiliationHoshina, K., University of Tokyo, Japanen_AU
local.contributor.affiliationYamanouchi, K, University of Tokyo, Japanen_AU
local.contributor.authoruidu4030223en_AU
local.description.notesImported from ARIESen_AU
local.description.refereedYes
local.identifier.absfor020204en_AU
local.identifier.ariespublicationMigratedxPub2758en_AU
local.identifier.citationvolume117en_AU
local.identifier.doi10.1063/1.1485064en_AU
local.identifier.scopusID2-s2.0-0037100747
local.publisher.urlhttps://www.aip.org/en_AU
local.type.statusPublished Versionen_AU

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