Synthesis, molecular structure, and reactivity of neutral and cationic areneosmium(II) complexes with diarylcarbenes as ligands

Weberndorfer, Birgit; Henig, Gerhard; Hockless, David; Bennett, Martin; Werner, Helmut

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Synthesis, molecular structure, and reactivity of neutral and cationic areneosmium(II) complexes with diarylcarbenes as ligands

Date

2003

Authors

Weberndorfer, Birgit

Henig, Gerhard

Hockless, David

Bennett, Martin

Werner, Helmut

Publisher

American Chemical Society

Abstract

While the dinuclear compounds [(η6-mes)Os{κ1-OC(O)CF3} (μ-Cl)]2 (2) and [(η6-mes)Os{κ1-OS(O)2 CF3}(μ-Cl)]2 (3), prepared from [(η6-mes)OsCl(η3-C3H5)] (1) and CF3CO2H or CF3SO3H by elimination of propene, are not suitable precursors for the synthes