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Metal coordination to bipyridyl carbynes

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dc.contributor.authorFrogley, Benjamin
dc.contributor.authorHill, Anthony
dc.date.accessioned2020-12-14T00:28:14Z
dc.date.issued2020-03-14
dc.description.abstractThe Pd0/AuI-mediated coupling of the stannylcarbyne [W([triple bond, length as m-dash]CSnnBu3)(CO)2(Tp*)] (1) and 6-bromo-2,2'-bipyridine or 6,6'-dibromo-2,2'-bipyridine gives new carbynes functionalised on the carbyne carbon(s) with a bipyridyl group. These new 'metallo-ligands' undergo protonation at the pyridyl nitrogens, metallation of the tungsten-carbon triple bond with [AuCl(SMe2)], and metallation of the bipyridyl moiety with K[PtCl3(C2H4)]·H2O, [ReBr(CO)5] and [MCl(COD]2 (M = Ir, Rh; COD = η4-cycloocta-1,5-diene).en_AU
dc.description.sponsorshipDP170102695 and DP190100723en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1477-9226en_AU
dc.identifier.urihttp://hdl.handle.net/1885/217123
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18010..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020).en_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rights© 2020 Royal Society of Chemistryen_AU
dc.sourceDalton transactionsen_AU
dc.titleMetal coordination to bipyridyl carbynesen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.issue10en_AU
local.bibliographicCitation.lastpage3283en_AU
local.bibliographicCitation.startpage3272en_AU
local.contributor.affiliationFrogley, B., Research School of Chemistry,The Australian National Universityen_AU
local.contributor.affiliationHill, A., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.authoruidu4030185en_AU
local.identifier.ariespublicationa383154xPUB11220
local.identifier.citationvolume49en_AU
local.identifier.doi10.1039/c9dt04744aen_AU
local.identifier.essn1477-9234en_AU
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/DTen_AU
local.type.statusAccepted Versionen_AU

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