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A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties

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Authors

Merhi, Areej
Grelaud, Guillaume
Green, Katy A.
Minh, Ngo Hoang
Reynolds, Michael
Ledoux, Isabelle
Barlow, Adam
Wang, Genmiao
Cifuentes, Marie P.
Humphrey, Mark

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Volume Title

Publisher

Royal Society of Chemistry

Abstract

A new Zn(ii) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ(2)-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.

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Source

Dalton transactions

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Access Statement

Open Access

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Restricted until