A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties
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Merhi, Areej
Grelaud, Guillaume
Green, Katy A.
Minh, Ngo Hoang
Reynolds, Michael
Ledoux, Isabelle
Barlow, Adam
Wang, Genmiao
Cifuentes, Marie P.
Humphrey, Mark
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Royal Society of Chemistry
Abstract
A new Zn(ii) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ(2)-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.
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Dalton transactions
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