Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand.

Mirzadeh, Nedaossadat; Bennett, Martin; Wagler, Jorg; Wachtler, Erik; Gerke, Birgit; Pottgen, Rainer; Bhargava, Suresh Kumar

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Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand.

Date

2013

Authors

Mirzadeh, Nedaossadat

Bennett, Martin

Wagler, Jorg

Wachtler, Erik

Gerke, Birgit

Pottgen, Rainer

Bhargava, Suresh Kumar

Publisher

Wiley-VCH Verlag GMBH

Abstract

A dinuclear Pd-Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC6F4AsPh 2]-, with palladium appears to be best described as PdI-SnIII or Pd0-SnIV.