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Chloroform as a hydrogen atom donor in Barton reductive decarboxylation reactions

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Date

2013

Authors

Ho, Junming
Zheng, Jingjing
Meana-Paneda, Ruben
Truhlar, Donald G
Ko, Eun Jung
Savage, G Paul
Williams, Craig
Coote, Michelle
Tsanaktsidis, J

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The utility of chloroform as both a solvent and a hydrogen atom donor in Barton reductive decarboxylation of a range of carboxylic acids was recently demonstrated (Ko, E. J. et al. Org. Lett. 2011, 13, 1944). In the present work, a combination of electron

Description

Keywords

Keywords: Alkyl radicals; Decarboxylation reactions; Direct dynamics; Electronic structure calculations; Experimental studies; Hydrogen-atom transfer; Kinetic control; Quantum-mechanical tunneling; Carboxylation; Carboxylic acids; Chlorine compounds; Electronic str

Citation

URI

http://hdl.handle.net/1885/63106

Collections

ANU Research Publications

Source

Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/jo400927y

Restricted until

2037-12-31

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01_Ho_Chloroform_as_a_hydrogen_atom_2013.pdf (581.75 KB)

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