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The transient current at the disk electrode under diffusion control: a new determination by the Cope-Tallman method

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dc.contributor.authorMahon, Peter
dc.contributor.authorOldham, Keith
dc.date.accessioned2015-12-13T23:06:16Z
dc.date.available2015-12-13T23:06:16Z
dc.date.issued2004
dc.date.updated2016-02-24T09:47:16Z
dc.description.abstractFor purposes of convolutive modelling, a need exists for polynomial functions relating to inlaid disc electrodes operating under diffusion-controlled conditions. To satisfy this need, the method pioneered by Cope and Tallman has been reimplemented. Data from that exercise, and from other sources, have been used to construct useful short- and long-time polynomial functions that together span the entire time range. To the extent possible, these functions have been compared with literature data and tested for internal consistency.
dc.identifier.issn0013-4686
dc.identifier.urihttp://hdl.handle.net/1885/85962
dc.publisherPergamon-Elsevier Ltd
dc.sourceElectrochimica Acta
dc.subjectKeywords: Computer simulation; Data reduction; Diffusion; Error analysis; Finite difference method; Functions; Polarization; Polynomials; Problem solving; Chronoamoerometry; Chronopotentiometry; Cope-Tallman method; Disk electrodes; Electrodes Chronoamperometry; Chronopotentiometry; Cope-Tallman method; Disk electrodes
dc.titleThe transient current at the disk electrode under diffusion control: a new determination by the Cope-Tallman method
dc.typeJournal article
local.bibliographicCitation.issue28
local.bibliographicCitation.lastpage5048
local.bibliographicCitation.startpage5041
local.contributor.affiliationMahon, Peter, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationOldham, Keith, Trent University
local.contributor.authoruidMahon, Peter, u4043257
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030604 - Electrochemistry
local.identifier.ariespublicationMigratedxPub14664
local.identifier.citationvolume49
local.identifier.doi10.1016/j.electacta.2004.06.005
local.identifier.scopusID2-s2.0-6344227997
local.type.statusPublished Version

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