Synthesis of conjugated diene complexes of ruthenium(0) derived from Ru(η6-naphthalene)(η4-1,5-COD): Z to E isomerisation of coordinated 1,3-pentadiene
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Hirano, Masafumi
Sakate, Yumiko
Inoue, Haruka
Arai, Yasutomo
Komine, Nobuyuki
Komiya, Sanshiro
Wang, Xian-qi
Bennett, Martin
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Elsevier
Abstract
The naphthalene complex of zerovalent ruthenium, [Ru(η6- C10H8)(η4-1,5-COD)] (1), readily reacts with 1,3-dienes in the presence of a ligand (L) to produce complexes [Ru(η4-cisoid-1,3-diene)(η4-1,5-COD)(L)] [1,3-diene = butadiene, 2,3-dimethylbutadien
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1 ,3-cyclohexadiene, 1 ,3-dienes, 1 ,3-pentadiene, Auxiliary ligands, Axial sites, Benzene-d 6, Conjugated diene, First-order rates, Isomerisation, Metal atoms, Single crystal x-ray structures, Square-pyramidal geometry, Vacant sites, Zerovalent, Benzene, 1,3-Pentadiene, Conjugated diene, E/Z isomerisation, Ruthenium(0)
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Journal of Organometallic Chemistry
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2037-12-31
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