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Rigid chiral carbocyclic clefts as building blocks for the construction of new supramolecular hosts

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dc.contributor.authorTry, Andrew C
dc.contributor.authorPainter, Leoni
dc.contributor.authorHarding, Margaret
dc.date.accessioned2015-12-13T22:26:23Z
dc.date.issued1998
dc.date.updated2015-12-11T08:22:03Z
dc.description.abstractThe synthesis and resolution of two chiral carbocyclic cleft molecules containing carbonyl groups on the periphery of the cavity are reported. These compounds are reminiscent of Troger's base but contain a smaller cleft and additional carbonyl (or alcohol) groups. X-ray crystal structures of the dibromo and dimethyl derivatives show that the dihedral angle between the two aromatic rings is 79°and 85°respectively. The dibromo derivative provides entry into new supramolecular hosts, via introduction of additional recognition groups into the cleft molecules.
dc.identifier.issn0040-4039
dc.identifier.urihttp://hdl.handle.net/1885/73494
dc.publisherElsevier
dc.sourceTetrahedron Letters
dc.subjectKeywords: carbonyl derivative; article; chirality; crystal structure; cyclization; molecular recognition; synthesis
dc.titleRigid chiral carbocyclic clefts as building blocks for the construction of new supramolecular hosts
dc.typeJournal article
local.bibliographicCitation.issue52
local.bibliographicCitation.lastpage9812
local.bibliographicCitation.startpage9809
local.contributor.affiliationTry, Andrew C, University of Sydney
local.contributor.affiliationPainter, Leoni, University of Sydney
local.contributor.affiliationHarding, Margaret, Administrative Division, ANU
local.contributor.authoruidHarding, Margaret, u4044881
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030500 - ORGANIC CHEMISTRY
local.identifier.ariespublicationf5625xPUB3714
local.identifier.citationvolume39
local.identifier.doi10.1016/s0040-4039(98)02179-0
local.identifier.scopusID2-s2.0-0032564537
local.type.statusPublished Version

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